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From my personal point of view, its a NO! Will you allow a man be her best lady? A man will wear the gown or normal manly clothes and stay behind her?
Bro I already have heard of such happening so you wont even be the first. Its just not ok, it is not lovely to behold.
Moreso, in church there should be order, let a man have his place and the woman her place.
Look for other creative ideas in terms of your dress sense, decoration, cake, reception order, photographs etc